Heterometallic coordination polymers as heterogeneous electrocatalysts

Heterometallic coordination polymers incorporating dipyrrin based heteroleptic copper and cobalt complexes: to Ag-π or not?

Using ligands based on either an acetylacetonate or a dipyrrin moiety appended with pyridyl groups, a series of novel heteroleptic copper(II) and cobalt(III) complexes combining both chelate units such as (acacpy(2))Cu(dpm-py) and (acacpy(2))Co(dpm-py)(2) (acacpy(2) = 1,3-bis(4-pyridyl)-1,3-propanedionate; dpm-py = 5-(4-pyridyl)dipyrrin) have been prepared and fully characterized. These two com...

Syntheses, structures, and magnetic properties of heterometallic coordination polymers with carboxyphosphonate linkers†

Five heterometallic coordination polymers were synthesized utilizing the multifunctional carboxyphosphonate ligand N-(phosphonomethyl)iminodiacetic acid (H4PMIDA), N(CH2PO(OH)2)(CH2COOH)2, with a coordinating nitrogen atom and two carboxylate and one phosphonate groups. The compounds were characterized structurally and magnetically. [Cu2M2(PMIDA)2(H2O)6]$3H2O for M 1⁄4 Mn (1-CuMn), Co (2-CuCo),...

Ionothermal synthesis , crystal structure , topology and catalytic property of heterometallic coordination polymers

Two novel Co(II) coordination polymers based on 1,4-bis(3-pyridylaminomethyl)benzene as electrocatalysts for oxygen evolution from water.

Based on the L (1,4-bis(3-pyridylaminomethyl)benzene) ligand, two MOFs formulated as Co(L)0.5(adip) (H2adip = adipic acid) (1) and Co2(L)2(5-bdc)2(H2O)2·H2O (2) (5-H2bdc = 5-nitroisophthalic acid) (2) were synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 features a uninodal 4-connected non-interpenetrated sql/Shubnikov tetragonal plane net with {4(4).6(2...

A series of Zn-4f heterometallic coordination polymers and a zinc complex containing a flexible mixed donor dicarboxylate ligand.

A new zinc compound, together with a corresponding series of Zn-4f heterometallic coordination polymers, namely, [Zn(H2PBDA)(PBDA)]n (1), {[Ln2(PBDA)2·2H2O] [Zn2(PBDA)2Cl2]}n [H2PBDA = 3-(pyridin-3-yl-oxy) benzene-1,2-dicarboxylic acid, and Ln = Pr(2), Nd(3), Eu(4), Gd(5), Dy(6), Ho(7), Er(8)] have been hydrothermally synthesized and characterized systematically. Polymers 2-8 feature two-dimens...